翻訳と辞書 Words near each other ・ Alma de Bretteville Spreckels ・ Alma de bronce ・ Alma de buxo ・ Alma De Groen ・ Alma de hierro ・ Alma de mi alma ・ Allyl-alcohol dehydrogenase ・ Allylamine ・ Allylcyclopentane ・ Allylescaline ・ Allylestrenol ・ Allylglycine ・ Allylguaiacol ・ Allylic rearrangement ・ Allylic stannane addition ・ Allylic strain ・ Allylmagnesium bromide ・ Allylnorpethidine ・ Allylpalladium chloride dimer ・ Allylprodine ・ Allyn ・ Allyn & Bacon ・ Allyn Abbott Young ・ Allyn and Betty Taylor Library ・ Allyn Ann McLerie ・ Allyn Capron ・ Allyn Condon ・ Allyn Cox ・ Allyn Ferguson ・ Allyn House Dictionary Lists mini英和辞書 mini和英辞書 Webster 1913 Latin-English FOLDOC Wikipedia English ウィキペディア

翻訳と辞書　辞書検索 [ 開発暫定版 ] スポンサード リンク Allylic strain ： ウィキペディア英語版 Allylic strain Allylic strain (also known as A1,3 strain, 1,3-allylic strain, or A-strain) in organic chemistry is a type of strain energy resulting from the interaction between a substituent on one end of an olefin with an allylic substituent on the other end.〔Eric V. Anslyn and Dennis A. Dougherty ''Modern Physical Organic Chemistry'' University Science Books, 2006.〕 If the substituents (R and R') are large enough in size, they can sterically interfere with each other such that one conformer is greatly favored over the other. Allyic strain was first recognized in the literature in 1965 by Johnson and Malhotra. The authors were investigating cyclohexane conformations including endocyclic and exocylic double bonds when they noticed certain conformations were disfavored due to the geometry constraints caused by the double bond.〔 Organic chemists capitalize on the rigidity resulting from allylic strain for use in asymmetric reactions.〔 == Quantifying Allylic Strain Energy == The "strain energy" of a molecule is a quantity that is difficult to precisely define, so the meaning of this term can easily vary depending on one's interpretation. Instead, an objective way to view the allylic strain of a molecule is through its conformational equilibrium. Comparing the heats of formation of the involved conformers, an overall ΔHeq can be evaluated. This term gives information about the relative stabilities of the involved conformers and the effect allylic strain has on equilibrium. Heats of formation can be determined experimentally though calorimetric studies; however, calculated enthalpies are more commonly used due to the greater ease of acquisition.〔 Different methods utizilized to estimate conformational equilibrium enthalpy include: the Westheimer method,〔Eliel, E. L.; Allinger, N. L.; Angyal, S. J.; Morrison, G. A. ''Conformational Analysis'' Interscience Publishers, Inc., New York, N. Y., 1965.〕 the homomorph method, and more simply—using estimated enthalpies of nonbonded interactions within a molecule. Because all of these methods are approximations, reported strain values for the same molecule can vary and should be used only to give a general idea of the strain energy. 抄文引用元・出典: フリー百科事典『 ウィキペディア（Wikipedia）』 ■ウィキペディアで「Allylic strain」の詳細全文を読む スポンサード リンク 翻訳と辞書 : 翻訳のためのインターネットリソース Copyright(C) kotoba.ne.jp 1997-2016. All Rights Reserved.